1-(1-(4-methoxyphenyl)allyl)benzene

Base Information

• Chemical Name: 1-(1-(4-methoxyphenyl)allyl)benzene
• CAS No.: 949568-24-5
• Molecular Formula: C₁₆H₁₈O₂
• Molecular Weight: 242.318
• Mol file: 949568-24-5.mol

Synonyms:1-(1-(4-methoxyphenyl)allyl)benzene

Chemical Property of 1-(1-(4-methoxyphenyl)allyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-(1-(4-methoxyphenyl)allyl)benzene

There total 15 articles about 1-(1-(4-methoxyphenyl)allyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

diethyl 3-phenylprop-2-enyl phosphate + 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane (213596-33-9) → 1-(1-(4-methoxyphenyl)allyl)benzene (949568-24-5)

Guidance literature:

With C₂₆H₂₂N₂O*F₆P^(1-)*H⁽¹⁺⁾; sodium methylate; copper(l) chloride; In tetrahydrofuran; at 30 ℃; for 16h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/anie.201103581

Reference yield: 48.0%

1-(1-(4-methoxyphenyl)allyl)benzene (949568-24-5) → (S)-3-(4-methoxyphenyl)-3-phenyl-1-propanol (949568-24-5)

Guidance literature:

1-(1-(4-methoxyphenyl)allyl)benzene; With borane-dimethyl sulfide complex; In tetrahydrofuran; at 0 - 20 ℃; for 1.16667h;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; at 0 - 20 ℃; for 1h;

DOI:10.1002/anie.201103581

Reference yield:

3-(4-methoxyphenyl)-3-phenylpropanal (92804-32-5) → (R)-3-(4-methoxyphenyl)-3-phenyl-1-propanol (1167442-89-8) + (S)-3-(4-methoxyphenyl)-3-phenyl-1-propanol (949568-24-5)

Guidance literature:

With methanol; sodium tetrahydroborate; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2011.10.051

upstream raw materials:

4-methoxy-trans-cinnamaldehyde

phenylboronic acid

2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane