benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

Base Information

Chemical Name:benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether
CAS No.:142399-14-2
Molecular Formula:C₃₁H₃₈OSSi
Molecular Weight:486.794
Hs Code.:

Synonyms:benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

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Technology Process of benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

There total 1 articles about benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141245-01-4
C₂₃H₂₈OS

: 768-33-2
phenyldimethylsilyl chloride

: 142399-14-2
benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; Yield given. Multistep reaction; 1.) THF, -78 deg C, 1 h, 2.) THF, 45 min;
DOI:10.1246/bcsj.65.929

Reference yield: 75.0%

: 142399-14-2
benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

: 141245-04-7
(2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-2,6-octadien-1-ol

Guidance literature:: With ammonia; lithium; at -78 ℃; for 0.25h;
DOI:10.1246/bcsj.65.929

Reference yield:

: 142399-14-2
benzyl (2Z,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

: 115362-62-4
cis-6-isopropenyl-3-methyl-2-cyclohexenol

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / Li, liquid NH₃ / 0.25 h / -78 °C

2: 83 percent / pyridinium dichromate (PDC) / CH₂Cl₂ / 12 h / Ambient temperature

3: TBAF / tetrahydrofuran / 3 h / Heating

With dipyridinium dichromate; tetrabutyl ammonium fluoride; ammonia; lithium; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.65.929