Dichlorophosphinoferrocene

Base Information

Chemical Name:Dichlorophosphinoferrocene
CAS No.:1291-31-2
Molecular Formula:C₁₀H₉Cl₂FeP
Molecular Weight:286.908
Hs Code.:
European Community (EC) Number:694-752-2
Mol file:1291-31-2.mol

Synonyms:Dichlorophosphinoferrocene;1291-31-2;MFCD20922898;P,P-Dichloroferrocenylphosphine, >=95% (T)

Suppliers and Price of Dichlorophosphinoferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Dichlorophosphinoferrocene, 98%
1g
$ 55.00

Strem Chemicals
Dichlorophosphinoferrocene, 98%
5g
$ 220.00

Sigma-Aldrich
P,P-Dichloroferrocenylphosphine ≥95% (T)
2g
$ 189.00

Sigma-Aldrich
P,P-Dichloroferrocenylphosphine ≥95% (T)
500mg
$ 49.70

Total 7 raw suppliers

Chemical Property of Dichlorophosphinoferrocene

Chemical Property:

Sensitive.:moisture sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:285.916828
Heavy Atom Count:14
Complexity:80.4

Purity/Quality:

99% ^*data from raw suppliers

Dichlorophosphinoferrocene, 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): 16508371
Hazard Codes:C,Xn
Statements: 14-20/21/22-34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][C]([CH]1)P(Cl)Cl.[Fe]

Technology Process of Dichlorophosphinoferrocene

There total 9 articles about Dichlorophosphinoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 83528-85-2
ferrocenylphosphane

: 1291-31-2
P,P-dichloroferrocenylphosphine

Guidance literature:: With phosgene; In dichloromethane; toluene; at -10 - 25 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.inorgchem.0c00276

Reference yield: 90.0%

: 142691-85-8
C₅H₅FeC₅H₄{PN(CH₃)C₂H₄N(CH₃)}

: 1291-31-2
P,P-dichloroferrocenylphosphine

Guidance literature:: With hydrogenchloride; In diethyl ether; HCl in Et2O is added slowly to a soln. of phosphoramide in Et2O (under Ar), mixt. is stirred for 2 h at room temp., then HCl in Et2O is added slowly under cooling at 0°C, stirring react. mixt. at room temp. within 2 h; ppt. is filtered, washed with Et2O, soln. is evapd., recrystn. from pentane, elem. anal.;

Reference yield: 90.0%

: C₅H₅FeC₅H₄{PN(CH₃)C₃H₆N(CH₃)}

: 1291-31-2
P,P-dichloroferrocenylphosphine

Guidance literature:: With hydrogenchloride; In diethyl ether; HCl in Et2O is added slowly to a soln. of phosphoramide in Et2O (under Ar), mixt. is stirred for 2 h at room temp., then HCl in Et2O is added slowly under cooling at 0°C, stirring react. mixt. at room temp. within 2 h; ppt. is filtered, washed with Et2O, soln. is evapd., recrystn. from pentane, elem. anal.;