phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Base Information

Chemical Name:phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside
CAS No.:105374-15-0
Molecular Formula:C₂₇H₃₂O₄SSi
Molecular Weight:480.7
Hs Code.:

Synonyms:phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Suppliers and Price of phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Chemical Property:

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Technology Process of phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

There total 5 articles about phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 105374-14-9
phenyl-β-D-erythro thioapiofuranoside

: 58479-61-1
tert-butylchlorodiphenylsilane

: 105374-15-0
phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 25 ℃; for 3h;
DOI:10.1021/jo00375a010

Reference yield:

: 4551-15-9
phenylthiotrimethylsilane

: 105374-15-0
phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 4.5 h / 0 - 23 °C

2: 60 percent / Dowex 50W-X₈ (acid form) / propan-2-ol; H₂O / 70 °C / Dowex 50W-X₈ ion exchange resin (acid form)

3: 80 percent / imidazole / dimethylformamide / 3 h / 25 °C

With 1H-imidazole; trimethylsilyl trifluoromethanesulfonate; Dowex 50W-X₈ (acid form); In dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00375a010

Reference yield:

: 91738-40-8
(3-C-acetoxymethyl)-1-O-acetyl-2,3-O-isopropylidene-β-D-erythrofuranose

: 105374-15-0
phenyl 3-C-((tert-butyldiphenylsilyl)oxy)methyl-β-D-thioerythrofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 4.5 h / 0 - 23 °C

2: 60 percent / Dowex 50W-X₈ (acid form) / propan-2-ol; H₂O / 70 °C / Dowex 50W-X₈ ion exchange resin (acid form)

3: 80 percent / imidazole / dimethylformamide / 3 h / 25 °C

With 1H-imidazole; trimethylsilyl trifluoromethanesulfonate; Dowex 50W-X₈ (acid form); In dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00375a010