3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

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Chemical Name:3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester
CAS No.:132672-33-4
Molecular Formula:C₂₉H₄₀N₂O₇Si₂
Molecular Weight:584.817
Hs Code.:

Synonyms:3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

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Chemical Property of 3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

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Technology Process of 3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

There total 5 articles about 3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 132672-32-3
2-Methyl-5-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-pent-3-yn-2-ol

: 99-33-2
3,5-dinitrobenoyl chloride

: 132672-33-4
3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

Guidance literature:: With dmap; In dichloromethane; at 0 ℃; for 0.416667h;
DOI:10.1021/jo00005a006

Reference yield:

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 132672-33-4
3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

2: 1) EtMgBr / 1) THF, 50 deg C, 50 min, 2) rt, 100 min

3: 89 percent / n-BuNH₂ / CuI, Pd(PPh₃)4 / 36 h / 40 °C

4: 98 percent / DMAP / CH₂Cl₂ / 0.42 h / 0 °C

With 2,6-dimethylpyridine; dmap; ethylmagnesium bromide; N-butylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane;
DOI:10.1021/jo00005a006

Reference yield:

: 117285-99-1
2-bromo-1-(2-propynyl)-cyclopent-2-en-1-ol

: 132672-33-4
3,5-Dinitro-benzoic acid 1,1-dimethyl-4-(1-triethylsilanyloxy-2-trimethylsilanylethynyl-cyclopent-2-enyl)-but-2-ynyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

2: 1) EtMgBr / 1) THF, 50 deg C, 50 min, 2) rt, 100 min

3: 89 percent / n-BuNH₂ / CuI, Pd(PPh₃)4 / 36 h / 40 °C

4: 98 percent / DMAP / CH₂Cl₂ / 0.42 h / 0 °C

With 2,6-dimethylpyridine; dmap; ethylmagnesium bromide; N-butylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane;
DOI:10.1021/jo00005a006