allylammonium bis(2-phenylethyl)diselenophosphinate

Base Information

• Chemical Name: allylammonium bis(2-phenylethyl)diselenophosphinate
• CAS No.: 1200778-44-4
• Molecular Formula: C₃H₇N*C₁₆H₁₉PSe₂
• Molecular Weight: 457.316
• Mol file: 1200778-44-4.mol

Synonyms:allylammonium bis(2-phenylethyl)diselenophosphinate

Chemical Property of allylammonium bis(2-phenylethyl)diselenophosphinate

Chemical Property:

Purity/Quality:

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Technology Process of allylammonium bis(2-phenylethyl)diselenophosphinate

There total 3 articles about allylammonium bis(2-phenylethyl)diselenophosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bis(2-phenylethyl)phosphine selenide (923023-81-8) + 1-amino-2-propene (107-11-9,30551-89-4) → allylammonium bis(2-phenylethyl)diselenophosphinate (1200778-44-4)

Guidance literature:

With hydrogen selenide; In tetrahydrofuran; ethanol; at 85 ℃; for 0.25h; Inert atmosphere;

DOI:10.1055/s-0029-1216948

Reference yield: 85.0%

bis(2-phenethyl)phosphine (93017-30-2) + 1-amino-2-propene (107-11-9,30551-89-4) → allylammonium bis(2-phenylethyl)diselenophosphinate (1200778-44-4)

Guidance literature:

With selenium; In ethanol; at 20 - 60 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1258232

Reference yield: 58.0%

bis(2-phenylethyl)phosphine selenide (923023-81-8) + 1-amino-2-propene (107-11-9,30551-89-4) → allylammonium bis(2-phenylethyl)diselenophosphinate (1200778-44-4) + 3-(diphenethylphosphoroselenoyl)propylamine (1494534-24-5) + bis(2-phenethyl)phosphine (93017-30-2)

Guidance literature:

In 1,4-dioxane; for 1h; Inert atmosphere; UV-irradiation;

DOI:10.1134/S1070363213100162

upstream raw materials:

bis(2-phenylethyl)phosphine selenide

1-amino-2-propene

bis(2-phenethyl)phosphine

Refernces

• 1、 Artemev, Alexander V.,Gusarova, Nina K.,Malysheva, Svetlana F.,Kraikivskii, Peter B.,Belogorlova, Nataliya A.,Trofimov, Boris A.. "Efficient general synthesis of alkylammonium diselenophosphinates via multicomponent one-pot reaction of secondary phosphines with elemental selenium and amines". supporting information; experimental part. p. 3724 - 3730. Retrieved 2011/01/03.