2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone

Base Information

Chemical Name:2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone
CAS No.:53884-91-6
Molecular Formula:C16H13N2O2+
Molecular Weight:265.2861
Hs Code.:
NSC Number:373507
DSSTox Substance ID:DTXSID30421007

Synonyms:NSC373507;53884-91-6;DTXSID30421007;NSC-373507

Suppliers and Price of 2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:264.089877630
Heavy Atom Count:20
Complexity:418

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C2C(O2)(C3=CC=CC=C3)C(=O)C=[N+]=[N-]

Technology Process of 2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone

There total 7 articles about 2-Diazo-1-(2,3-diphenyloxiran-2-yl)ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60727-80-2
Sodium; (2S,3R)-2,3-diphenyl-oxirane-2-carboxylate

: 53884-91-6
2-Diazo-1-((2S,3R)-2,3-diphenyl-oxiranyl)-ethanone

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / CCl₄ / 0 °C

2: diethyl ether

With pyridine; In tetrachloromethane; diethyl ether;
DOI:10.1016/0040-4020(80)80105-0

Reference yield:

: Potassium; (2S,3S)-2,3-diphenyl-oxirane-2-carboxylate

: 53884-91-6
2-Diazo-1-((2S,3S)-2,3-diphenyl-oxiranyl)-ethanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) 4N HCl; 2.) Et₃N / 1.) 0 deg C, water;

2: diethyl ether / 1.) -20 deg C; 2.) r.t., 2 days

With hydrogenchloride; triethylamine; In diethyl ether;
DOI:10.1016/0040-4020(80)80105-0

Reference yield:

: Potassium; (2S,3R)-2,3-diphenyl-oxirane-2-carboxylate

: 53884-91-6
2-Diazo-1-((2S,3R)-2,3-diphenyl-oxiranyl)-ethanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) 4N HCl; 2.) Et₃N / 1.) 0 deg C, water, 2.) ether;

2: diethyl ether / 1.) -20 deg C; 2.) r.t., 2 days

With hydrogenchloride; triethylamine; In diethyl ether;
DOI:10.1016/0040-4020(80)80105-0