[(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)]

Base Information

• Chemical Name: [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)]
• CAS No.: 1309604-25-8
• Molecular Formula: C₃₃H₄₇ClN₄ORu
• Molecular Weight: 652.285
• Mol file: 1309604-25-8.mol

Synonyms:[(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)]

Chemical Property of [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)]

There total 1 articles about [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)] (942516-63-4) + benzyl azide (622-79-7) → [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)] (1309604-25-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1002/cctc.201500935

Reference yield:

[(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2N=NN=NCH2Ph)] (1309604-25-8) + benzylamine (100-46-9) → [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(NH3)2] + N-benzylidene benzylamine (780-25-6)

Guidance literature:

In tetrahydrofuran-d8; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.7b00403

upstream raw materials:

di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)]

benzyl azide

Downstream raw materials:

N-benzylidene benzylamine