(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

Base Information

Chemical Name:(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane
CAS No.:1374991-67-9
Molecular Formula:C₂₉H₄₈O₄Si₂
Molecular Weight:516.869
Hs Code.:

Synonyms:(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

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Chemical Property of (6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

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Technology Process of (6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

There total 7 articles about (6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1374991-73-7
C₂₇H₄₄O₃Si₂

: 107-30-2
chloromethyl methyl ether

: 1374991-67-9
(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20 ℃; for 5h;
DOI:10.1016/j.tetasy.2012.03.005

Reference yield:

: C₁₃H₂₀O₅

: 1374991-67-9
(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 10 steps

1: palladium 10% on activated carbon; hydrogen / ethanol / 2 h

2: water; acetic acid / 12 h / 20 °C

3: sodium periodate / methanol / 2 h / 0 - 20 °C

4: sodium tetrahydroborate / methanol / 0.5 h / 0 °C

5: 1H-imidazole / dichloromethane / 0.25 h / 0 °C

6: boron trichloride / dichloromethane / 0.03 h / 0 °C

7: sodium periodate / methanol; water / 0.5 h / 0 °C

8: sodium tetrahydroborate / methanol / 0.5 h / 0 °C

9: dmap; triethylamine / dichloromethane / 3 h / 0 - 20 °C

10: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 5 h / 0 - 20 °C

With 1H-imidazole; dmap; sodium tetrahydroborate; sodium periodate; palladium 10% on activated carbon; water; hydrogen; boron trichloride; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; In methanol; ethanol; dichloromethane; water;
DOI:10.1016/j.tetasy.2012.03.005

Reference yield:

: C₂₁H₂₈O₃Si

: 1374991-67-9
(6S,7S)-6-(methoxymethoxy)-2,2,7,10,10,11,11-heptamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium tetrahydroborate / methanol / 0.5 h / 0 °C

2: dmap; triethylamine / dichloromethane / 3 h / 0 - 20 °C

3: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 5 h / 0 - 20 °C

With dmap; sodium tetrahydroborate; triethylamine; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane;
DOI:10.1016/j.tetasy.2012.03.005