(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

Base Information

Chemical Name:(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne
CAS No.:1059635-96-9
Molecular Formula:C₂₂H₃₄Sn
Molecular Weight:417.222
Hs Code.:

Synonyms:(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

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Technology Process of (Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

There total 1 articles about (Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1059635-86-7
(Z)-1-(trimethylsilyl)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

: 1059635-96-9
(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

Guidance literature:: With potassium fluoride; In methanol; refluxed for 5 h; evapd. (vac.), extd. with Et2O, washed (H2O), dried (MgSO4), evapd. (vac.), flash-chromd. (silica gel, light petroleum); elem. anal.;
DOI:10.1016/j.jorganchem.2008.06.002

Reference yield: 80.0%

: 128-08-5
N-Bromosuccinimide

: Schwartz's reagent

: 1059635-96-9
(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

: 1059636-07-5
(1E,3Z)-1-bromo-3-(tributylstannyl)-4-phenyl-1,3-butadiene

Guidance literature:: In tetrahydrofuran; a flask charged with Zr complex under Ar, THF added, Sn compd. added, stirred for 40 min at room temp., a soln. of C4H4N(O)2Br added dropwise at0°C, stirred at room temp. for 1 h; dild. with Et2O, filtered (silica gel), concd., chromd. (TLC, silica gel, petroleum ether); elem. anal.;
DOI:10.1016/j.jorganchem.2008.06.002

Reference yield: 78.0%

: Schwartz's reagent

: 1059635-96-9
(Z)-3-(tributylstannyl)-4-phenylbut-3-en-1-yne

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 1059636-19-9
(1E,3Z)-1-iodo-3-(tributylstannyl)-4-phenyl-1,3-butadiene

Guidance literature:: In tetrahydrofuran; a flask charged with Zr complex under Ar, THF added, Sn compd. added, stirred for 40 min at room temp., a soln. of I2 added dropwise at 0°C, stirred at room temp. for 1 h; dild. with Et2O, filtered (silica gel), concd., chromd. (TLC, silica gel, petroleum ether); elem. anal.;
DOI:10.1016/j.jorganchem.2008.06.002