4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

Base Information

Chemical Name:4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl
CAS No.:949583-14-6
Molecular Formula:C₄₈H₄₅IO₂
Molecular Weight:780.789
Hs Code.:

Synonyms:4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

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Chemical Property of 4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

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Technology Process of 4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

There total 3 articles about 4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 949583-13-5
C₅₂H₅₅N₃O₂

: 949583-14-6
4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

Guidance literature:: With iodine; In various solvent(s); at 80 ℃;
DOI:10.1021/ol071296h

Reference yield:

: 936565-47-8
[4-(4-tert-butylphenylmethoxy)phenyl]boronic acid

: 949583-14-6
4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / sodium carbonate / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / 1,2-dimethoxy-ethane / 100 °C

2: 67 percent / iodine / various solvent(s) / 80 °C

With iodine; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; 1: Suzuki-Miyaura coupling;
DOI:10.1021/ol071296h

Reference yield:

: 669692-34-6
1-[3,5-dibromo-4-(phenylethynyl)phenyl]-3,3-diethyltriazene

: 949583-14-6
4,4″-bis((4-tert-butylphenyl)methoxy)-5′-iodo-2′-(2-phenylethynyl)-1,1′:3′,1″-terphenyl

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / sodium carbonate / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / 1,2-dimethoxy-ethane / 100 °C

2: 67 percent / iodine / various solvent(s) / 80 °C

With iodine; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; 1: Suzuki-Miyaura coupling;
DOI:10.1021/ol071296h