(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

Base Information

Chemical Name:(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene
CAS No.:134153-72-3
Molecular Formula:C₁₄H₁₃NO₃S
Molecular Weight:275.328
Hs Code.:

Synonyms:(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

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Chemical Property of (1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

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Technology Process of (1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

There total 5 articles about (1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 134153-71-2
(1R,4S,7R)-3-(2-(R)-hydroxy-2-phenylacetyl)-7-(methylthio)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

: 134153-72-3
(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

Guidance literature:: With pyridine; osmium(VIII) oxide; for 24h; Ambient temperature;
DOI:10.1021/ja00081a017

Reference yield:

: 124412-11-9
1-(methylthio)cyclopenta-2,4-diene

: 134153-72-3
(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 24 percent / Bu₄NIO₄ / CCl₄; methanol / 1 h / 0 °C

2: 32 percent / OsO₄, pyridine / 24 h / Ambient temperature

With pyridine; osmium(VIII) oxide; tetrabutylammonium periodite; In methanol; tetrachloromethane;
DOI:10.1021/ja00081a017

Reference yield:

: 20698-91-3
(R)-methyl mandelate

: 134153-72-3
(1R,4S,7R)-7-(methylthio)-3-(oxophenylacetyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

Guidance literature:: Multi-step reaction with 3 steps

1: 74 percent / NH₂OH / methanol / 96 h / Ambient temperature

2: 24 percent / Bu₄NIO₄ / CCl₄; methanol / 1 h / 0 °C

3: 32 percent / OsO₄, pyridine / 24 h / Ambient temperature

With pyridine; osmium(VIII) oxide; hydroxylamine; tetrabutylammonium periodite; In methanol; tetrachloromethane;
DOI:10.1021/ja00081a017