Technology Process of C20H31BrO6
There total 7 articles about C20H31BrO6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 2 steps
1: RuBr2{(R)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl}; hydrogen / ethanol / 44 h / 45 °C / 30003 Torr / High-pressure bomb
2: lithium triethylborohydride / tetrahydrofuran / 0 - 20 °C
With
RuBr2{(R)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl}; hydrogen; lithium triethylborohydride;
In
tetrahydrofuran; ethanol;
DOI:10.1016/j.tet.2011.09.058
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: oxygen; ozone / dichloromethane / 0.07 h / -78 °C
1.2: 3 h / -78 - 20 °C
1.3: -78 - 20 °C
2.1: RuBr2{(R)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl}; hydrogen / ethanol / 44 h / 45 °C / 30003 Torr / High-pressure bomb
3.1: lithium triethylborohydride / tetrahydrofuran / 0 - 20 °C
With
RuBr2{(R)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl}; hydrogen; oxygen; lithium triethylborohydride; ozone;
In
tetrahydrofuran; ethanol; dichloromethane;
1.3: Roskamp rearrangement;
DOI:10.1016/j.tet.2011.09.058