[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

Base Information

Chemical Name:[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane
CAS No.:494839-24-6
Molecular Formula:C₂₀H₃₂F₃N₄P
Molecular Weight:416.47
Hs Code.:

Synonyms:[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

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Chemical Property of [o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

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Technology Process of [o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

There total 1 articles about [o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 56183-63-2
bis(diisopropylamino)chlorophosphine

: (ortho-trifluoromethylphenyl)diazomethane

: 494839-24-6
[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

Guidance literature:: (ortho-trifluoromethylphenyl)diazomethane; With lithium hexamethyldisilazane; In diethyl ether; at -100 ℃; for 0.5h;

bis(diisopropylamino)chlorophosphine; In diethyl ether; at -100 - 20 ℃; Further stages.;
DOI:10.1021/ja0281986

Reference yield: 64.0%

: di(rhodium)tetracarbonyl dichloride

: 494839-24-6
[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

: 512204-57-8
(CO)3Cl₂Rh₂(P(N(C₃H₇)2)2(C(N₂)C₆H₄CF₃))

Guidance literature:: In diethyl ether; to ether soln. diazophosphine was added ether soln. (Rh(μ-Cl(CO)2)2 at room temp. and stirred for 30 min; pentane was added and soln. was cooled to -20°C;
DOI:10.1021/om0210558

Reference yield: 52.0%

: di(rhodium)tetracarbonyl dichloride

: 494839-24-6
[o-(trifluoromethyl)phenyl][bis(diisopropylamino)phodphino]diazomethane

: 512204-56-7
(CO)2ClRh(P(N(C₃H₇)2)2(C(N₂)C₆H₄CF₃))

Guidance literature:: In diethyl ether; to ether soln. diazophosphine was added ether soln. (Rh(μ-Cl(CO)2)2 at -50°C and stirred for 30 min; soln. was cooled to -80°C;
DOI:10.1021/om0210558