6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose

Base Information

• Chemical Name: 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose
• CAS No.: 138560-19-7
• Molecular Formula: C₃₅H₃₆O₅
• Molecular Weight: 536.668
• Mol file: 138560-19-7.mol

Synonyms:6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose

Chemical Property of 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose

There total 9 articles about 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-gulo/ido-hept-6-enose, cyclic 1,3-propanediyl mercaptals (138560-18-6,138560-30-2) → 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-gulo-hept-6-enose (138560-20-0) + 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose (138560-19-7)

Guidance literature:

With N-chloro-succinimide; silver nitrate; In water; acetonitrile; for 0.75h;

DOI:10.1016/S0040-4020(01)88278-8

Reference yield:

C38H40NO4S(1+)*I(1-) → 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose (138560-19-7)

Guidance literature:

C₃₈H₄₀NO₄S⁽¹⁺⁾*I^(1-); With sodium tetrahydroborate; In methanol; at 0 ℃; for 0.5h;

With water; silver nitrate; In water; acetonitrile; at 23 ℃; for 0.166667h;

DOI:10.1016/j.tet.2012.11.004

Reference yield:

2,3,4-tri-O-benzyl-5,6-dideoxy-D-xylo-hex-5-enose (73111-58-7,130861-06-2,73111-15-6) → 6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-ido-hept-6-enose (138560-19-7)

Guidance literature:

Multi-step reaction with 2 steps

2: 40 percent / N-chlorosuccinimde (NCS), AgNO₃ / acetonitrile; H₂O / 0.75 h

With N-chloro-succinimide; silver nitrate; In water; acetonitrile;

DOI:10.1016/S0040-4020(01)88278-8

upstream raw materials:

6,7-dideoxy-2,3,4,5-tetrakis-O-(phenylmethyl)-D-gulo/ido-hept-6-enose, cyclic 1,3-propanediyl mercaptals

2,3,4-tri-O-benzyl-5,6-dideoxy-D-xylo-hex-5-enose

benzyl bromide

C₃₀H₂₉NO₄S

Downstream raw materials:

(2S,3R,4S,5R)-2,3,4,5-tetra(benzyloxy)hept-6-enoic acid

(2S,3R,4S,5R)-2,3,4,5-tetra(benzyloxy)-N-((S)-2-oxoazepa-3-yl)hept-6-enamide

(2S,3R,4S,5R,E)-2,3,4,5-tetra(benzyloxy)-8-methyl-N-((S)-2-oxoazepan-3-yl)non-6-enamide

1,2-dideoxy-2-(hydroxymethyl)-1-(methylamino)-scyllo-inositol