Technology Process of N,N'-bis[(5-bromopyrid-2-yl)methyl]-N,N'-dimethylpropane-1,3-diamine
There total 1 articles about N,N'-bis[(5-bromopyrid-2-yl)methyl]-N,N'-dimethylpropane-1,3-diamine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: sodium tetrahydroborate / methanol / 4 h / 0 - 20 °C
2: thionyl chloride / toluene / 3 h / 20 °C
3: potassium carbonate / acetonitrile / 72 h / 20 °C / Inert atmosphere
With
sodium tetrahydroborate; thionyl chloride; potassium carbonate;
In
methanol; toluene; acetonitrile;
DOI:10.1002/chem.201101272
- Guidance literature:
-
N,N'-bis[(5-bromopyrid-2-yl)methyl]-N,N'-dimethylpropane-1,3-diamine;
With
bis(η3-allyl-μ-chloropalladium(II)); caesium carbonate; triphenylphosphine; sodium iodide;
In
N,N-dimethyl-formamide; toluene;
at 80 ℃;
for 12h;
Inert atmosphere;
zinc(II) 5,15-di-p-tolyl-10-phenyl-20-[4',4',5',5'-tetramethyl-(1',2',3'-dioxaborolan-2'-yl)]porphyrin;
In
N,N-dimethyl-formamide; toluene;
for 12h;
Inert atmosphere;
Reflux;
DOI:10.1002/chem.201101272
