methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

Base Information

Chemical Name:methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate
CAS No.:146564-11-6
Molecular Formula:C₁₉H₁₅NO₄S₂
Molecular Weight:385.464
Hs Code.:

Synonyms:methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

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Chemical Property of methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

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Technology Process of methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

There total 9 articles about methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: methyl 2,3-dihydro-3-hydroxy-3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

: 146564-11-6
methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

Guidance literature:: With toluene-4-sulfonic acid; In benzene; Heating;
DOI:10.1016/0040-4039(93)85109-A

Reference yield: 54.0%

: 146564-09-2
methyl <3-acetyl-1-(phenylsulfonyl)-1H-indol-4-ylthio>acetate

: 146564-11-6
methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

: methyl 2,3-dihydro-3-hydroxy-3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

Guidance literature:: With piperidine; acetic acid; In benzene; for 24h; Heating;
DOI:10.1248/cpb.42.271

Reference yield:

: 16851-82-4
N-phenylsulfonylpyrrole

: 146564-11-6
methyl 3-methyl-5-phenylsulfonyl-5H-thiopyrano<4,3,2-c,d>indole-2-carboxylate

Guidance literature:: Multi-step reaction with 8 steps

1: 64 percent / TiCl₄ / CH₂Cl₂ / 2 h / -78 °C

2: 100 percent / aq. LiOH / tetrahydrofuran / 48 h / Ambient temperature

3: 100 percent / (COCl)2, pyridine / benzene / 0.5 h / Ambient temperature

4: 86 percent / SnCl₄ / CH₂Cl₂ / 0.33 h / 0 °C

5: 95 percent / BF₃*Et₂O / benzene / 24 h / Ambient temperature

6: 94 percent / AlCl₃ / 1,2-dichloro-ethane / 15 h / Ambient temperature

7: 100 percent / Et₃N / benzene / 15 h / Heating

8: 98 percent / TsOH*H₂O / benzene / 10 h / Heating

With pyridine; lithium hydroxide; aluminium trichloride; oxalyl dichloride; boron trifluoride diethyl etherate; titanium tetrachloride; tin(IV) chloride; toluene-4-sulfonic acid; triethylamine; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; benzene;
DOI:10.1248/cpb.42.271