2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine

Base Information

• Chemical Name: 2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine
• CAS No.: 137522-85-1
• Molecular Formula: C₂₁H₂₀N₈O₃
• Molecular Weight: 432.442
• Mol file: 137522-85-1.mol

Synonyms:137522-85-1;BRN 5464430;2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine;2-[[4,6-bis[2-[(2-methoxyphenyl)methylidene]hydrazinyl]-1,3,5-triazin-2-yl]oxy]acetonitrile;((4,6-Bis(((2-methoxyphenyl)methylene)hydrazino)-1,3,5-triazin-2-yl)oxy)acetonitrile;2-((4,6-Bis(2-(2-methoxybenzylidene)hydrazinyl)-1,3,5-triazin-2-yl)oxy)acetonitrile;Acetonitrile, ((4,6-bis(((2-methoxyphenyl)methylene)hydrazino)-1,3,5-triazin-2-yl)oxy)-;2-[[4,6-bis[(2E)-2-[(2-methoxyphenyl)methylidene]hydrazinyl]-1,3,5-triazin-2-yl]oxy]acetonitrile

Chemical Property of 2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 688.3°Cat760mmHg
• PKA: 9.78±0.10(Predicted)
• Flash Point: 370.1°C
• PSA: 138.93000
• Density: 1.3g/cm³
• LogP: 2.82918
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 10
• Exact Mass: 432.16583653
• Heavy Atom Count: 32
• Complexity: 610

Purity/Quality:

99%min ^*data from raw suppliers

((4,6-BIS(((2-METHOXYPHENYL)METHYLENE)HYDRAZINO)-1,3,5-TRIAZIN-2-YL)OXY)ACETONITRILE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC=C1C=NNC2=NC(=NC(=N2)OCC#N)NN=CC3=CC=CC=C3OC
• Isomeric SMILES: COC1=CC=CC=C1/C=N/NC2=NC(=NC(=N2)OCC#N)N/N=C/C3=CC=CC=C3OC

Technology Process of 2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine

There total 2 articles about 2,4-Di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

2,4-dihydrazino-6-cyanomethoxy-s-traizine (137522-84-0) + ortho-anisaldehyde (135-02-4) → 2,4-di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine (137522-85-1)

Guidance literature:

With hydrogenchloride; In ethanol; water; for 0.0833333h;

DOI:10.1007/BF00768985

Reference yield:

2,4,6-tricyanomethoxy-s-triazine (891-64-5) → 2,4-di-(2-methoxybenzylidene)hydrazino-6-cyanomethoxy-s-triazine (137522-85-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / 98percent hydrazine hydrate / ethanol / 0.17 h / Heating

2: 37 percent / HCl / ethanol; H₂O / 0.08 h

With hydrogenchloride; hydrazine hydrate; In ethanol; water;

DOI:10.1007/BF00768985

upstream raw materials:

2,4-dihydrazino-6-cyanomethoxy-s-traizine

ortho-anisaldehyde

2,4,6-tricyanomethoxy-s-triazine

Refernces