1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

Base Information

Chemical Name:1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside
CAS No.:1323240-30-7
Molecular Formula:C₄₆H₅₇NO₁₄
Molecular Weight:847.957
Hs Code.:

Synonyms:1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

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Chemical Property of 1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

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Technology Process of 1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

There total 3 articles about 1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1323240-27-2
1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

: 108-24-7
acetic anhydride

: 1323240-30-7
1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

Guidance literature:: With zinc; at 20 ℃; for 8h;
DOI:10.1016/j.tet.2011.05.133

Reference yield:

: 1323240-19-2
1-methyl-1-cyclopropylmethyl 3,4,6-tri-O-benzyl-D-mannopyranoside

: 1323240-30-7
1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: N-iodo-succinimide; trifluorormethanesulfonic acid / dichloromethane / 0.75 h / 0 °C / Inert atmosphere; Molecular sieve

2: zinc / 8 h / 20 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; zinc; In dichloromethane;
DOI:10.1016/j.tet.2011.05.133

Reference yield:

: 187022-49-7
(2R,3S,4R,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)-5-(((2,2,2-trichloroethoxy)carbonyl)amino)tetrahydro-2H-pyran-3,4-diyl diacetate

: 1323240-30-7
1-methyl-1-cyclopropylmethyl [3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: N-iodo-succinimide; trifluorormethanesulfonic acid / dichloromethane / 0.75 h / 0 °C / Inert atmosphere; Molecular sieve

2: zinc / 8 h / 20 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; zinc; In dichloromethane;
DOI:10.1016/j.tet.2011.05.133