2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

Base Information

Chemical Name:2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene
CAS No.:199440-13-6
Molecular Formula:C₃₀H₂₈Br₂O₂
Molecular Weight:580.359
Hs Code.:

Synonyms:2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

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Chemical Property of 2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

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Technology Process of 2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

There total 1 articles about 2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 66790-58-7
2-bromo-1-(bromomethyl)-3-methylbenzene

: 2325-10-2
(S,S)-hydrobenzoin

: 199440-13-6
2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

Guidance literature:: With sodium hydride; benzylamine; Yield given. Multistep reaction; 1.) THF, room temperature, 30 min, 2.) THF, reflux;
DOI:10.1021/jo9713619

Reference yield: 63.0%

: 199440-13-6
2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

: (7S,8S)-1,14-Dimethyl-7,8-diphenyl-5,7,8,10-tetrahydro-6,9-dioxa-dibenzo[a,c]cyclodecene

Guidance literature:: With oxygen; In tetrahydrofuran; 1.) -78 deg C, 2 h, 2.) 0 deg C, 1 h;
DOI:10.1021/jo9713619

Reference yield:

: 199440-13-6
2-bromo-1-({2-[(2-bromo-3-methylbenzyl)oxy]-1,2-diphenylethoxy}methyl)-3-methylbenzene

: (S,S,S)-2,2'-bi-o-tolyl-1,1-diphenyl bisoxazoline

Guidance literature:: Multi-step reaction with 7 steps

1: 63 percent / CuCN, O₂ / tetrahydrofuran / 1.) -78 deg C, 2 h, 2.) 0 deg C, 1 h

2: 87 percent / H₂ / Pd/C / methanol / 24 h

3: 94 percent / NMO, TPAP / CH₂Cl₂ / 0.25 h / Ambient temperature

4: 97 percent / 2-methyl-2-butene, NaClO₂, NaH₂PO₄ / 2-methyl-propan-2-ol

5: 88 percent / (COCl)2, DMF / CH₂Cl₂ / 8 h / Ambient temperature

6: Et₃N / CH₂Cl₂

7: Burgess reagent / tetrahydrofuran / Ambient temperature

With sodium chlorite; sodium dihydrogenphosphate; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; oxalyl dichloride; Burgess Reagent; hydrogen; oxygen; triethylamine; N,N-dimethyl-formamide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; tert-butyl alcohol;
DOI:10.1021/jo9713619