(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

Base Information

Chemical Name:(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate
CAS No.:1298085-76-3
Molecular Formula:C₃₉H₄₃F₃O₆
Molecular Weight:664.762
Hs Code.:

(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

Synonyms:(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

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Chemical Property of (2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

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Technology Process of (2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

There total 3 articles about (2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1298085-71-8
(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-4,10-dimethyl-7-methylene-9-[(1S)-1-phenylethoxy]-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}-2,11-tridecadien-3-yl benzoate

: 1298085-76-3
(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

Guidance literature:: With pentamethylbenzene,; boron trichloride; In dichloromethane; at -78 ℃; Inert atmosphere;
DOI:10.1002/chem.201003264

Reference yield:

: C₂₁H₂₂O₃

: 1298085-76-3
(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: trimethylsilyl trifluoromethanesulfonate / toluene / 6 h / -78 °C / Inert atmosphere

1.2: 16 h / -78 °C / Inert atmosphere

1.3: 0.33 h / Inert atmosphere; Reflux

2.1: pentamethylbenzene,; boron trichloride / dichloromethane / -78 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; pentamethylbenzene,; boron trichloride; In dichloromethane; toluene;
DOI:10.1002/chem.201003264

Reference yield:

: C₂₂H₂₁F₃O₃

: 1298085-76-3
(2Z,4R,5R,9S,10S,11Z)-11-(benzoyloxy)-9-hydroxy-4,10-dimethyl-7-methylidene-5-{(1R)-1-[4-(trifluoromethyl)phenyl]ethoxy}trideca-2,11-dien-3-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: trimethylsilyl trifluoromethanesulfonate / toluene / 6 h / -78 °C / Inert atmosphere

1.2: 16 h / -78 °C / Inert atmosphere

1.3: 0.33 h / Inert atmosphere; Reflux

2.1: pentamethylbenzene,; boron trichloride / dichloromethane / -78 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; pentamethylbenzene,; boron trichloride; In dichloromethane; toluene;
DOI:10.1002/chem.201003264