(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

Base Information

Chemical Name:(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate
CAS No.:1647022-01-2
Molecular Formula:C₂₁H₂₄O₅
Molecular Weight:356.419
Hs Code.:

Synonyms:(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

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Chemical Property of (Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

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Technology Process of (Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

There total 3 articles about (Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1192068-12-4
dimethyl 2-(but-2-yn-1-yl)-2-(3-methylbuta-1,2-dien-1-yl)malonate

: 10365-98-7,1107579-37-2
3-methoxyphenylboronic acid

: 1647022-01-2
(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

Guidance literature:: With triphenylboroxine; 2,3,5,6-tetrafluoro-1,4-benzoquinone; palladium diacetate; In 1,4-dioxane; water; at 80 ℃; for 20h; stereoselective reaction; Microwave irradiation;
DOI:10.1002/anie.201404264

Reference yield:

: 107428-17-1
dimethyl propargylmalonate

: 1647022-01-2
(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; tetrahydrofuran / 0.92 h / 0 - 20 °C

1.2: Reflux

2.1: palladium diacetate; 2,3,5,6-tetrafluoro-1,4-benzoquinone; triphenylboroxine / water; 1,4-dioxane / 20 h / 80 °C / Microwave irradiation

With triphenylboroxine; 2,3,5,6-tetrafluoro-1,4-benzoquinone; palladium diacetate; sodium hydride; In tetrahydrofuran; 1,4-dioxane; water; mineral oil;
DOI:10.1002/anie.201404264

Reference yield:

: 6214-32-0
1-bromo-3-methylbuta-1,2-diene

: 1647022-01-2
(Z)-dimethyl 3-(prop-1-en-2-yl)-4-(1-(m-methoxyphenyl)ethylidene)cyclopent-2-ene-1,1-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; tetrahydrofuran / 0.92 h / 0 - 20 °C

1.2: Reflux

2.1: palladium diacetate; 2,3,5,6-tetrafluoro-1,4-benzoquinone; triphenylboroxine / water; 1,4-dioxane / 20 h / 80 °C / Microwave irradiation

With triphenylboroxine; 2,3,5,6-tetrafluoro-1,4-benzoquinone; palladium diacetate; sodium hydride; In tetrahydrofuran; 1,4-dioxane; water; mineral oil;
DOI:10.1002/anie.201404264