1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose

Base Information

• Chemical Name: 1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose
• CAS No.: 1428634-25-6
• Molecular Formula: C₂₃H₂₈N₂O₇
• Molecular Weight: 444.485
• Mol file: 1428634-25-6.mol

Synonyms:1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose

Chemical Property of 1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose

There total 1 articles about 1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromonitromethane (563-70-2) + C22H25NO5 → C23H28N2O7 (1428634-30-3) + L-gulofuranose + 1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose (1428634-25-6)

Guidance literature:

bromonitromethane; With indium; zinc; In tetrahydrofuran; for 0.333333h; Sonication;

C₂₂H₂₅NO₅; In tetrahydrofuran; for 4h; Sonication;

DOI:10.1016/j.tetlet.2013.02.041

Reference yield: 87.0%

1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-6-nitro-α-D-mannofuranose (1428634-25-6) → 6-amino-1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-α-D-mannofuranose (1428634-26-7)

Guidance literature:

With pyrrolidine; samarium diiodide; potassium carbonate; rochelle salt; In tetrahydrofuran; diethyl ether; water; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.02.041

upstream raw materials:

bromonitromethane

Downstream raw materials:

6-amino-1-O-benzyl-5,6-deoxy-2,3-di-O-isopropylidene-5-p-methoxyphenylamino-α-D-mannofuranose