(2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane

Base Information

Chemical Name:(2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane
CAS No.:136174-88-4
Molecular Formula:C₃₄H₃₆O₅
Molecular Weight:524.657
Hs Code.:
DSSTox Substance ID:DTXSID00996499
Nikkaji Number:J427.157B

Synonyms:DTXSID00996499;136174-88-4;beta-D-arabino-Hexopyranoside, 2-methylphenyl 2-deoxy-3,4,6-tris-O-(phenylmethyl)-

Suppliers and Price of (2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane

Chemical Property:

XLogP3:6.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:12
Exact Mass:524.25627424
Heavy Atom Count:39
Complexity:654

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=CC=C1OC2CC(C(C(O2)COCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5
Isomeric SMILES:CC1=CC=CC=C1O[C@H]2C[C@H]([C@@H]([C@H](O2)COCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5

Technology Process of (2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane

There total 5 articles about (2R,3S,4R,6S)-6-(2-methylphenoxy)-3,4-bis(phenylmethoxy)-2-(phenylmethoxymethyl)oxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 136201-61-1
o-cresyl 2-deoxy-2-selenophenyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside

: 136174-88-4
o-cresyl 2-deoxy-3,4,6-tri-O-benzyl-β-D-gluco-pyranoside

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; at 100 ℃;
DOI:10.1021/jo00020a003 DOI:10.1021/ja00113a013

Reference yield: 62.0%

: p-toulenesulfonyl 3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranoside

: 95-48-7,77504-84-8
ortho-cresol

: 136174-88-4
o-cresyl 2-deoxy-3,4,6-tri-O-benzyl-β-D-gluco-pyranoside

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; diethylene glycol dimethyl ether; at -78 - 20 ℃; for 18.25h; stereoselective reaction;

Reference yield:

: p-toluenesulfonyl 3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranoside

: 95-48-7,77504-84-8
ortho-cresol

: 136174-88-4
o-cresyl 2-deoxy-3,4,6-tri-O-benzyl-β-D-gluco-pyranoside

Guidance literature:: ortho-cresol; With potassium hexamethylsilazane; In tetrahydrofuran; diethylene glycol dimethyl ether; at -78 ℃; for 0.25h; Inert atmosphere;

p-toluenesulfonyl 3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranoside; In tetrahydrofuran; diethylene glycol dimethyl ether; at -78 - 20 ℃; for 18h; Inert atmosphere;
DOI:10.1021/ol4018547