(4-(tert-butyl)phenyl)carbamoyl azide

Base Information

• Chemical Name: (4-(tert-butyl)phenyl)carbamoyl azide
• CAS No.: 1613145-27-9
• Molecular Formula: C₁₁H₁₄N₄O
• Molecular Weight: 218.258
• Mol file: 1613145-27-9.mol

Synonyms:(4-(tert-butyl)phenyl)carbamoyl azide

Chemical Property of (4-(tert-butyl)phenyl)carbamoyl azide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (4-(tert-butyl)phenyl)carbamoyl azide

There total 2 articles about (4-(tert-butyl)phenyl)carbamoyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

4-tert-Butylbenzaldehyde (939-97-9) → (4-(tert-butyl)phenyl)carbamoyl azide (1613145-27-9)

Guidance literature:

With tert.-butylhydroperoxide; trimethylsilylazide; potassium iodide; In ethyl acetate; at 75 ℃; for 24h; Schlenk technique;

DOI:10.1002/cjoc.201600914

Reference yield: 68.0%

methyl 3-(4-(tert-butyl)phenyl)-3-oxopropanoate (200280-57-5) + trimethylsilylazide (4648-54-8) → (4-(tert-butyl)phenyl)carbamoyl azide (1613145-27-9)

Guidance literature:

With ammonium cerium (IV) nitrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; In ethyl acetate; at 60 ℃; for 36h; under 760.051 Torr; Schlenk technique; Molecular sieve;

DOI:10.1021/ol5014476

upstream raw materials:

methyl 3-(4-(tert-butyl)phenyl)-3-oxopropanoate

trimethylsilylazide

4-tert-Butylbenzaldehyde