(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

Base Information

Chemical Name:(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane
CAS No.:106470-49-9
Molecular Formula:C₃₈H₃₉ClOS₂
Molecular Weight:611.312
Hs Code.:

Synonyms:(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

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Chemical Property of (Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

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Technology Process of (Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

There total 4 articles about (Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 106470-47-7,106565-07-5
(Z)-(1SR,3RS,5RS,6RS,7RS)-6-hydroxy-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

: 106470-49-9
(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

Guidance literature:: With methanesulfonyl chloride; triethylamine; In dichloromethane; for 0.5h;
DOI:10.1021/jo00381a027

Reference yield:

: 76-83-5
trityl chloride

: 106470-49-9
(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / pyridine / 18 h / 23 °C

2: 95 percent Spectr_. / n-BuLi / tetrahydrofuran / 1.25 h / -20 °C

3: 100 percent / triethylamine, methanesulfonyl chloride / CH₂Cl₂ / 0.5 h

With pyridine; n-butyllithium; methanesulfonyl chloride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00381a027

Reference yield:

: 106470-45-5,106566-14-7
(Z)-6-hydroxy-7-(7-hydroxy-2-heptenyl)-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

: 106470-49-9
(Z)-(1SR,3RS,5RS,6RS,7RS)-6-chloro-7-<7-(triphenylmethoxy)-2-heptenyl>-3-phenyl-2,4-dithiabicyclo<3.2.1>octane

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / pyridine / 18 h / 23 °C

2: 95 percent Spectr_. / n-BuLi / tetrahydrofuran / 1.25 h / -20 °C

3: 100 percent / triethylamine, methanesulfonyl chloride / CH₂Cl₂ / 0.5 h

With pyridine; n-butyllithium; methanesulfonyl chloride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00381a027