3-bromophenyl phenyl selenide

Base Information

• Chemical Name: 3-bromophenyl phenyl selenide
• CAS No.: 856074-00-5
• Molecular Formula: C₁₂H₉BrSe
• Molecular Weight: 312.067
• Mol file: 856074-00-5.mol

Synonyms:3-bromophenyl phenyl selenide

Chemical Property of 3-bromophenyl phenyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 3-bromophenyl phenyl selenide

There total 3 articles about 3-bromophenyl phenyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

diphenyl diselenide (1666-13-3) + (3-bromophenyl)boronic acid (89598-96-9) → 3-bromophenyl phenyl selenide (856074-00-5)

Guidance literature:

With potassium carbonate; In water; at 70 ℃; for 8h;

DOI:10.1016/j.tetlet.2014.12.055

Reference yield: 85.0%

→ 3-bromophenyl phenyl selenide (856074-00-5)

Guidance literature:

With trichloroisocyanuric acid; In tetrahydrofuran; at 25 ℃; for 4h;

Reference yield: 82.0%

Phenylselenyl bromide (34837-55-3) + (3-bromophenyl)boronic acid (89598-96-9) → 3-bromophenyl phenyl selenide (856074-00-5)

Guidance literature:

With caesium carbonate; In PEG-400; at 80 ℃; for 8h; chemoselective reaction;

DOI:10.1246/cl.2012.585

upstream raw materials:

Phenylselenyl bromide

(3-bromophenyl)boronic acid

diphenyl diselenide

Downstream raw materials:

1-[3-(phenylselanyl)phenylselanyl]-4-methoxybenzene

Phenyl-(3-hydroxy-phenyl)-selenid

Refernces

• 1、 Sun, Nan,Zheng, Kai,Sun, Pengyuan,Chen, Yang,Jin, Liqun,Hu, Baoxiang,Shen, Zhenlu,Hu, Xinquan. "Trichloroisocyanuric Acid-Promoted Synthesis of Arylselenides and Aryltellurides from Diorganyl Dichalcogenides and Arylboronic Acids at Ambient Temperature". . p. 3577 - 3584. Retrieved 2021/06/15.
• 2、 Harsha Vardhan Reddy,Satish,Ramesh,Karnakar,Nageswar. "Magnetically separable CuFe2O4 nanoparticle catalyzed CSe cross coupling in reusable PEG medium". experimental part. p. 585 - 587. Retrieved 2012/07/30.