Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

Base Information

Chemical Name:Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester
CAS No.:132627-63-5
Molecular Formula:C₁₆H₁₈O₇
Molecular Weight:322.315
Hs Code.:

Synonyms:Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

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Technology Process of Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

There total 2 articles about Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 132602-75-6
Methyl 2,3-di-O-acetyl-4-O-benzoyl-6-deoxy-2-C-methyl-α-D-xylo-hex-5-enopyranoside

: 132627-63-5
Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

Guidance literature:: With mercury(II) diacetate; acetic acid; In water; acetone; Heating;
DOI:10.1246/cl.1991.17

Reference yield:

: 132602-71-2
methyl 2,3-di-O-acetyl-4-O-benzoyl-6-bromo-6-deoxy-2-C-methyl-α-D-glucopyranoside

: 132627-63-5
Benzoic acid (1S,2S,3S,4S)-2-acetoxy-3,4-dihydroxy-3-methyl-6-oxo-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Bu₄NI, NaI, 4A molecular sieves 2) DBU / 1) 2) DMSO, 80 deg C

2: 70 percent / Hg(OAc)2, AcOH / acetone; H₂O / Heating

With 4 A molecular sieve; mercury(II) diacetate; tetra-(n-butyl)ammonium iodide; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium iodide; In water; acetone;
DOI:10.1246/cl.1991.17