phenyltris[(isopropyl)amino]phosphanium bromide

Base Information

• Chemical Name: phenyltris[(isopropyl)amino]phosphanium bromide
• CAS No.: 154106-21-5
• Molecular Formula: Br*C₁₅H₂₉N₃P
• Molecular Weight: 362.293
• Mol file: 154106-21-5.mol

Synonyms:phenyltris[(isopropyl)amino]phosphanium bromide

Chemical Property of phenyltris[(isopropyl)amino]phosphanium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyltris[(isopropyl)amino]phosphanium bromide

There total 1 articles about phenyltris[(isopropyl)amino]phosphanium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Dichlorophenylphosphine (644-97-3) + isopropylamine (75-31-0) → phenyltris[(isopropyl)amino]phosphanium bromide (154106-21-5)

Guidance literature:

Dichlorophenylphosphine; With bromine; In dichloromethane; at -10 ℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;

isopropylamine; With triethylamine; In dichloromethane; at -10 - 20 ℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/anie.201805479

Reference yield: 98.0%

phenyltris[(isopropyl)amino]phosphanium bromide (154106-21-5) → phenyltris[(isopropyl)amino]phosphanium hexafluorophosphate

Guidance literature:

With potassium hexafluorophosphate; In methanol; water; at 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/anie.201805479

Reference yield: 64.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + sodium tetraphenyl borate (143-66-8) + phenyltris[(isopropyl)amino]phosphanium bromide (154106-21-5) → [(η-p-cymene)Ru(η(2)-(iPrN)2PPh(NHiPr))]BPh4 (200942-57-0)

Guidance literature:

With n-BuLi; In tetrahydrofuran; methanol; hexane; N2-atmosphere; stirring (room temp., 15 min), Ru-compd. addn. (-78°C), stirring (room temp., 1 h), evapn. (vac.), MeOH and NaBPh4 addn., stirring (30 min); evapn. (vac.), washing (ether), CH2Cl2 addn., chromy. (SiO2, CH2Cl2), evapn. (vac.), crystn. (MeOH); elem. anal.;

DOI:10.1021/om970819u

upstream raw materials:

Dichlorophenylphosphine

isopropylamine

Downstream raw materials:

[(η-p-cymene)Ru(η(2)-(iPrN)2PPh(NHiPr))]BPh4