Technology Process of (R)-6-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-hexanal
There total 9 articles about (R)-6-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-hexanal which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) O3, 2.) BH3*SMe2 / 1.) CH2Cl2, -78 deg C, 2 h, 2.) CH2Cl2, 0 deg C, 3 h
2: 100 percent / DMAP, Et3N / CH2Cl2 / Ambient temperature
3: 100 percent / aq. K2CO3 / methanol / 4 h / Heating
4: 17.5 g / pyridinium dichromate, 4A molecular sieves / CH2Cl2 / 1 h / Ambient temperature
With
dmap; dipyridinium dichromate; dimethylsulfide borane complex; 4 A molecular sieve; potassium carbonate; ozone; triethylamine;
In
methanol; dichloromethane;
DOI:10.1021/ja9533609
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 100 percent / pyridine, DMAP / CH2Cl2 / 0.75 h / 0 °C
2: 1.) O3, 2.) BH3*SMe2 / 1.) CH2Cl2, -78 deg C, 2 h, 2.) CH2Cl2, 0 deg C, 3 h
3: 100 percent / DMAP, Et3N / CH2Cl2 / Ambient temperature
4: 100 percent / aq. K2CO3 / methanol / 4 h / Heating
5: 17.5 g / pyridinium dichromate, 4A molecular sieves / CH2Cl2 / 1 h / Ambient temperature
With
pyridine; dmap; dipyridinium dichromate; dimethylsulfide borane complex; 4 A molecular sieve; potassium carbonate; ozone; triethylamine;
In
methanol; dichloromethane;
DOI:10.1021/ja9533609
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 100 percent / DMAP, Et3N / CH2Cl2 / Ambient temperature
2: 100 percent / aq. K2CO3 / methanol / 4 h / Heating
3: 17.5 g / pyridinium dichromate, 4A molecular sieves / CH2Cl2 / 1 h / Ambient temperature
With
dmap; dipyridinium dichromate; 4 A molecular sieve; potassium carbonate; triethylamine;
In
methanol; dichloromethane;
DOI:10.1021/ja9533609
