tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane

Base Information

• Chemical Name: tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane
• CAS No.: 115234-28-1
• Molecular Formula: C₂₆H₃₈O₃Si
• Molecular Weight: 426.671
• Mol file: 115234-28-1.mol

Synonyms:tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane

Chemical Property of tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane

There total 2 articles about tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(Z)-8,8-Dimethoxy-oct-2-en-1-ol (115234-27-0) + tert-butylchlorodiphenylsilane (58479-61-1) → tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane (115234-28-1)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; for 2h; from 0 deg C to r.t.;

DOI:10.1016/S0040-4039(00)96700-5

Reference yield:

(Z)-8,8-Dimethoxy-oct-2-enoic acid methyl ester (115234-26-9) → tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane (115234-28-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / diisobutylaluminium hydride / cyclohexane; CH₂Cl₂ / 0.25 h / -78 °C

2: 85 percent / dimethylformamide / 2 h / Ambient temperature

With diisobutylaluminium hydride; In dichloromethane; cyclohexane; N,N-dimethyl-formamide;

Reference yield: 88.0%

tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane (115234-28-1) → (Z)-8-(tert-Butyl-diphenyl-silanyloxy)-oct-6-enal (115234-29-2)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; for 24h; Ambient temperature;

DOI:10.1016/S0040-4039(00)96700-5

upstream raw materials:

(Z)-8,8-Dimethoxy-oct-2-en-1-ol

tert-butylchlorodiphenylsilane

(Z)-8,8-Dimethoxy-oct-2-enoic acid methyl ester

Downstream raw materials:

(Z)-8-(tert-Butyl-diphenyl-silanyloxy)-oct-6-enal

(2E,8Z)-10-(tert-Butyl-diphenyl-silanyloxy)-deca-2,8-dienal

(6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-3-oxo-tetradeca-6,12-dienoic acid methyl ester

(6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-3-oxo-5-(tetrahydro-pyran-2-yloxy)-tetradeca-6,12-dienoic acid methyl ester