triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

Base Information

Chemical Name:triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane
CAS No.:1005481-71-9
Molecular Formula:C₂₄H₃₇NO₃SSi
Molecular Weight:447.714
Hs Code.:

Synonyms:triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

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Chemical Property of triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

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Technology Process of triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

There total 1 articles about triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 1005481-63-9
C₁₅H₁₇NO₃S

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 1005481-71-9
triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

Guidance literature:: C₁₅H₁₇NO₃S; triisopropylsilyl trifluoromethanesulfonate; In tetrahydrofuran; at 20 ℃; for 1h;

With lithium diisopropyl amide; In tetrahydrofuran; at 20 ℃; Further stages.;
DOI:10.1021/ja0782605

Reference yield: 80.0%

: 1005481-71-9
triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

: (5RS,6SR)-8-triisopropylsiloxy-3-methanesulfonyl-7-methyl-6-phenyl-3-azabicyclo[3.3.0]octa-1,7-diene

Guidance literature:: With 4 A molecular sieve; tungsten hexacarbonyl; tributyl-amine; In toluene; at 20 ℃; UV-irradiation;
DOI:10.1021/ja0782605

Reference yield:

: 1005481-71-9
triisopropyl-[(5Z,7E)-4-methanesulfonyl-7-methyl-8-phenyl-4-azaocta-5,7-dien-1-yn-6-yloxy]silane

: (1RS,5SR,6RS)-8-triisopropylsiloxy-2-methanesulfonyl-7-methyl-6-phenyl-2-azabicyclo[3.3.0]octa-3,7-diene

: (1RS,5SR,6SR)-8-triisopropylsiloxy-2-methanesulfonyl-7-methyl-6-phenyl-2-azabicyclo[3.3.0]octa-3,7-diene

Guidance literature:: With 4 A molecular sieve; tungsten hexacarbonyl; In toluene; at 20 ℃; Title compound not separated from byproducts.; UV-irradiation;
DOI:10.1021/ja0782605