Tetrabutylammonium tetraphenylborate

Base Information

• Chemical Name: Tetrabutylammonium tetraphenylborate
• CAS No.: 15522-59-5
• Molecular Formula: C40H56BN
• Molecular Weight: 561.702
• European Community (EC) Number: 239-562-9
• DSSTox Substance ID: DTXSID30165858
• Mol file: 15522-59-5.mol

Synonyms:Tetrabutylammonium tetraphenylborate;15522-59-5;tetrabutylazanium;tetraphenylboranuide;EINECS 239-562-9;tetra-n-butylammonium tetraphenylborate;tetrabutylammoniumtetraphenylborate;Tetraphenylboron tetrabutylammonium;SCHEMBL14916;DTXSID30165858;ZHCCBGAUZWZGQV-UHFFFAOYSA-N;C24H20B.C16H36N;MFCD00011749;AKOS015915675;HY-W111436;AS-70988;C24-H20-B.C16-H36-N;CS-0179359;T1480;D95259;A855071;J-009180;1-Butanaminium, N,N,N-Tributyl-, Tetraphenylborate(1-)

Chemical Property of Tetrabutylammonium tetraphenylborate

Chemical Property:

• Appearance/Colour: white crystals or powder
• Melting Point: 230-236 °C(lit.)
• PSA: 0.00000
• LogP: 8.06760
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Hygroscopic
• Solubility.: acetonitrile: 0.1 g/mL, clear, colorless
• Water Solubility.: Soluble in pyridine, acetone, water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 16
• Exact Mass: 561.4505810
• Heavy Atom Count: 42
• Complexity: 418

Purity/Quality:

97% ^*data from raw suppliers

Tetrabutylammonium tetraphenylborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.CCCC[N+](CCCC)(CCCC)CCCC
• Uses: Tetrabutylammonium tetraphenylborate (CAS# 15522-59-5) is an organic electrolyte, and an electrotunable compound, allowing for its use in the preparation of interesting materials such as electrotunable nanoplasmonic liquid mirrors.

Technology Process of Tetrabutylammonium tetraphenylborate

There total 5 articles about Tetrabutylammonium tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.3%

tetrabutylammomium bromide (1643-19-2) + sodium tetraphenyl borate (143-66-8) → tetrabutylammonium tetraphenylborate (15522-59-5)

Guidance literature:

In chlorobenzene; at 25 ℃; Temperature; Solvent;

Reference yield: 90.0%

tetra-n-butylammonium bromide (1643-19-2) + sodium tetraphenyl borate (143-66-8) → tetrabutylammonium tetraphenylborate (15522-59-5)

Guidance literature:

In acetone; Refluxing of mixt. (15 min).; Filtn., addn. of H2O gives white cryst. ppt., recrystn. (acetone-H2O, acetone-diethyl ether).;

Reference yield:

tetra-n-butylammonium hydroxide + sodium tetraphenyl borate (143-66-8) → tetrabutylammonium tetraphenylborate (15522-59-5) + sodium hydroxide (1310-73-2)

Guidance literature:

In acetone; potentiometric titration;

DOI:10.1021/ac60312a036

upstream raw materials:

tetrabutylammomium bromide

sodium tetraphenyl borate

tetra-n-butylammonium bromide

Downstream raw materials:

biphenyl

3,3’,5,5’-tetrakis(trifluoromethyl)biphenyl