4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

Base Information

Chemical Name:4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester
CAS No.:439675-15-7
Molecular Formula:C₁₂H₁₇BrSe₂Si
Molecular Weight:427.176
Hs Code.:

Synonyms:4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

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Chemical Property of 4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

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Technology Process of 4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

There total 3 articles about 4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

: 4-bromoselenobenzoic acid O-methyl ester

: 439675-12-4
bis[2-(trimethylsilyl)ethyl]-diselenide

: 439675-15-7
4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

Guidance literature:: bis[2-(trimethylsilyl)ethyl]-diselenide; With diisobutylaluminium hydride; In toluene; at 30 ℃; for 0.166667h;

4-bromoselenobenzoic acid O-methyl ester; In toluene; at 30 ℃; for 3h; Further stages.;
DOI:10.1021/ja026110i

Reference yield:

: 18156-67-7
(2-bromoethyl)trimethylsilane

: 439675-15-7
4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1.074 g / Li₂Se₂ / CH₂Cl₂; tetrahydrofuran / 0 - 30 °C

2.1: DIBAL-H / toluene / 0.17 h / 30 °C

2.2: 8 percent / toluene / 3 h / 30 °C

With dilithium diselenide; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ja026110i

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 439675-15-7
4-bromodiselenobenzoic acid Se-2-(trimethylsilyl)ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: CBr₄; PPh₃ / CH₂Cl₂ / 0.37 h / 0 °C

2.1: 1.074 g / Li₂Se₂ / CH₂Cl₂; tetrahydrofuran / 0 - 30 °C

3.1: DIBAL-H / toluene / 0.17 h / 30 °C

3.2: 8 percent / toluene / 3 h / 30 °C

With dilithium diselenide; carbon tetrabromide; diisobutylaluminium hydride; triphenylphosphine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ja026110i