3,4-didehydro-β-cyclo-homogeraniol

Base Information

• Chemical Name: 3,4-didehydro-β-cyclo-homogeraniol
• CAS No.: 60814-40-6
• Molecular Formula: C₁₁H₁₈O
• Molecular Weight: 166.263
• Mol file: 60814-40-6.mol

Synonyms:3,4-didehydro-β-cyclo-homogeraniol

Chemical Property of 3,4-didehydro-β-cyclo-homogeraniol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4-didehydro-β-cyclo-homogeraniol

There total 9 articles about 3,4-didehydro-β-cyclo-homogeraniol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-β-ionone (79-77-6,14901-07-6) → 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on (17283-81-7) + 3,4-didehydro-β-cyclo-homogeraniol (60814-40-6) + 2,4,4-trimethyl-3-(2'-hydroxymethyl)-2-cyclohexene (472-65-1) + 3-hydroxy-β-cyclo-homogeraniol + 3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-ol (83646-52-0) + 3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-one (75203-87-1)

Guidance literature:

With sodium nitrate; potassium dihydrogenphosphate; D-glucose; cornsteep liquor; Lasiodiplodia theobromae ATCC 28570; potassium chloride; In water; at 28 ℃; for 96h; Mechanism; biotransformation at pH=6.2-6.5;

DOI:10.1002/hlca.19820650532

Reference yield:

3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-ol (83646-52-0) → 3,4-didehydro-β-cyclo-homogeraniol (60814-40-6) + 1,5,5-trimethyl-9-oxa-bicyclo<4.3.0>non-2-en

Guidance literature:

With potassium hydrogensulfate; hydroquinone; In dimethyl sulfoxide; at 180 ℃; for 0.25h;

DOI:10.1002/hlca.19820650532

Reference yield:

2,6,6-trimethyl-1,3-cyclohexadieneacetic acid (19355-56-7) → 3,4-didehydro-β-cyclo-homogeraniol (60814-40-6)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; Ambient temperature;

upstream raw materials:

2,4,4-trimethyl-3-(2'-hydroxymethyl)-2-cyclohexene

3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-ol

2,6,6-trimethyl-1,3-cyclohexadieneacetic acid

(E)-β-ionone