TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE

Base Information

• Chemical Name: TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE
• CAS No.: 1678-82-6
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Hs Code.: 2902199090
• Mol file: 1678-82-6.mol

Synonyms:p-Menthane,trans- (8CI); 1-Isopropyl-trans-4-methylcyclohexane;trans-1-Isopropyl-4-methylcyclohexane; trans-p-Menthane

Chemical Property of TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE

Chemical Property:

• Melting Point: -86.3°C
• Refractive Index: 1.4366
• Boiling Point: 170 °C
• Flash Point: 38°C
• PSA: 0.00000
• Density: 0,79 g/cm3
• LogP: 3.46870

Purity/Quality:

99% ^*data from raw suppliers

TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE

There total 248 articles about TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

cis epoxyde du carvomenthene (3626-19-5,4680-25-5,4959-34-6,5034-17-3,5034-18-4,51424-68-1) → Menthane (99-82-1,1678-82-6,6069-98-3,129939-70-4,129939-71-5) + carvomenthone (499-70-7) + cis p-menthanol (3901-95-9) + 5-isoprpyl-2-methylcyclohexan-1-ol (499-69-4,1126-39-2,1126-40-5,1126-41-6,1845-59-6,3127-80-8,3858-43-3,3858-45-5,3858-47-7,3858-49-9,5563-78-0,42846-32-2,60320-28-7,116783-34-7) + 5-isopropyl-2-methylcyclohexan-1-ol (499-69-4,1126-39-2,1126-40-5,1126-41-6,1845-59-6,3127-80-8,3858-43-3,3858-45-5,3858-47-7,3858-49-9,5563-78-0,42846-32-2,60320-28-7,116783-34-7)

Guidance literature:

With hydrogen; palladium on activated charcoal; In cyclohexane; at 20 ℃; under 760 Torr; Rate constant;

DOI:10.1016/S0040-4020(01)98846-5

Reference yield: 43.0%

trans epoxyde du carvomenthene (3626-19-5,4680-25-5,4959-34-6,5034-17-3,5034-18-4,51424-68-1) → Menthane (99-82-1,1678-82-6,6069-98-3,129939-70-4,129939-71-5) + carvomenthone (499-70-7) + 5-isopropyl-2-methylcyclohexan-1-ol (499-69-4,1126-39-2,1126-40-5,1126-41-6,1845-59-6,3127-80-8,3858-43-3,3858-45-5,3858-47-7,3858-49-9,5563-78-0,42846-32-2,60320-28-7,116783-34-7) + 5-isopropyl-2-methylcyclohexan-1-ol (499-69-4,1126-39-2,1126-40-5,1126-41-6,1845-59-6,3127-80-8,3858-43-3,3858-45-5,3858-47-7,3858-49-9,5563-78-0,42846-32-2,60320-28-7,116783-34-7)

Guidance literature:

With hydrogen; palladium on activated charcoal; In cyclohexane; at 20 ℃; under 760 Torr;

DOI:10.1016/S0040-4020(01)98846-5

Reference yield: 12.0%

cis epoxyde du carvomenthene (3626-19-5,4680-25-5,4959-34-6,5034-17-3,5034-18-4,51424-68-1) → Menthane (99-82-1,1678-82-6,6069-98-3,129939-70-4,129939-71-5) + carvomenthone (499-70-7) + cis p-menthanol (3901-95-9) + 5-isoprpyl-2-methylcyclohexan-1-ol (499-69-4,1126-39-2,1126-40-5,1126-41-6,1845-59-6,3127-80-8,3858-43-3,3858-45-5,3858-47-7,3858-49-9,5563-78-0,42846-32-2,60320-28-7,116783-34-7)

Guidance literature:

With hydrogen; palladium on activated charcoal; In isopropyl alcohol; at 20 ℃; under 760 Torr; Further byproducts given;

DOI:10.1016/S0040-4020(01)98846-5

upstream raw materials:

pulegone

p-menth-1-ene

8-bromo-p-menthane

Terpinolene

Downstream raw materials:

(Z)-p-menthan-4-ol

(Z)-4-isopropyl-1-methylcyclohexan-1-ol

cis p-menthanol

isomenthone

Refernces

• 1、 Nagai. "". . p. 2628. Retrieved 1970.
• 2、 Alexander,Pinkus. "-". . p. 1786,1787. Retrieved 1949.
• 3、 Sutar, Papri,Bakuru, Vasudeva Rao,Yadav, Pooja,Laha, Subhajit,Kalidindi, Suresh Babu,Maji, Tapas Kumar. "Nanocomposite Hydrogel of Pd@ZIF-8 and Laponite: Size-Selective Hydrogenation Catalyst under Mild Conditions". supporting information. p. 3268 - 3272. Retrieved 2021/01/21.
• 4、 Akhtar, Naved,Begum, Wahida,Chauhan, Manav,Manna, Kuntal,Newar, Rajashree,Rawat, Manhar Singh. "Chemoselective and Tandem Reduction of Arenes Using a Metal–Organic Framework-Supported Single-Site Cobalt Catalyst". supporting information. . Retrieved 2022/01/19.