Technology Process of C33H32O6
There total 1 articles about C33H32O6 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C32H30O6; trimethylsulphonium iodide;
With
n-butyllithium;
In
tetrahydrofuran; hexanes;
at 0 ℃;
for 1.16667h;
Inert atmosphere;
With
zinc(II) iodide;
In
benzene;
at 25 ℃;
for 0.0833333h;
Inert atmosphere;
DOI:10.1002/anie.201103575
- Guidance literature:
-
With
sodium chlorite; sodium dihydrogenphosphate; recorcinol;
In
tetrahydrofuran; water; tert-butyl alcohol;
at 25 ℃;
DOI:10.1002/anie.201103575
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: sodium dihydrogenphosphate; sodium chlorite; recorcinol / tetrahydrofuran; water; tert-butyl alcohol / 25 °C
2.1: (Et2SI)2Cl*SbCl6 / acetonitrile / 0.02 h / 25 °C / Inert atmosphere
3.1: boron tribromide / dichloromethane / 24 h / 25 °C / Inert atmosphere
4.1: tetra-(n-butyl)ammonium iodide; potassium carbonate / acetone / 12 h / 25 - 56 °C / Inert atmosphere
5.1: n-butyllithium / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere
5.2: 0.33 h / -78 °C / Inert atmosphere
6.1: triethylsilane; boron trifluoride diethyl etherate / dichloromethane / 0.17 h / -78 - 25 °C / Inert atmosphere; Heating
7.1: palladium 10% on activated carbon; hydrogen / methanol; ethyl acetate / 12 h / 25 °C / 760.05 Torr
8.1: boron trifluoride diethyl etherate; boron trichloride / methanol; dichloromethane / 2.5 h / 25 °C / Inert atmosphere
With
triethylsilane; sodium chlorite; sodium dihydrogenphosphate; n-butyllithium; palladium 10% on activated carbon; (Et2SI)2Cl*SbCl6; boron trifluoride diethyl etherate; hydrogen; boron trichloride; boron tribromide; tetra-(n-butyl)ammonium iodide; potassium carbonate; recorcinol;
In
tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; acetone; acetonitrile; tert-butyl alcohol;
1.1: Pinnick oxidation reaction;
DOI:10.1002/anie.201103575
