allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Base Information

Chemical Name:allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester
CAS No.:312731-92-3
Molecular Formula:C₄₇H₆₀Cl₃NO₇Si
Molecular Weight:885.44
Hs Code.:

allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Synonyms:allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Suppliers and Price of allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

There total 12 articles about allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 106-95-6
allyl bromide

: 312732-20-0
{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

: 312731-92-3
allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Guidance literature:: With potassium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 1h;
DOI:10.1021/ja0013879

Reference yield:

: 6635-20-7
isonitrovanillin

: 312731-92-3
allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 96 percent / HBr; AcOH / H₂O / 8 h / Heating

2: 85 percent / NaH / dimethylformamide

3: 95 percent / pyridine / CH₂Cl₂ / 0 - 20 °C

4: 80 percent / dimethylformamide / 1 h

5: 94 percent / NaBH₄ / tetrahydrofuran / 0.08 h / 0 °C

6: 86 percent / NaH / tetrahydrofuran; dimethylformamide / 2 h / 20 °C

7: 38 percent / DIBAL-H / toluene / 0.25 h / 0 °C

8: 64 percent / NaH / dimethylformamide / 20 °C

9: 90 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

10: 99 percent / H₂ / Raney-Ni / methanol; tetrahydrofuran / 8.5 h

11: 95 percent / K₂CO₃ / CH₂Cl₂ / 1 h / 0 °C

12: 87 percent / KH / dimethylformamide / 1 h / 0 °C

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; hydrogen bromide; hydrogen; potassium hydride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; acetic acid; nickel; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja0013879

Reference yield:

: 116313-85-0
3,4-dihydroxy-5-nitrobenzaldehyde

: 312731-92-3
allyl-{3-benzyloxy-5-benzyloxymethyl-2-[1-(4-methoxy-benzyloxymethyl)-2-triisopropylsilanyloxy-ethyl]-phenyl}-carbamic acid 2,2,2-trichloro-ethyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: 85 percent / NaH / dimethylformamide

2: 95 percent / pyridine / CH₂Cl₂ / 0 - 20 °C

3: 80 percent / dimethylformamide / 1 h

4: 94 percent / NaBH₄ / tetrahydrofuran / 0.08 h / 0 °C

5: 86 percent / NaH / tetrahydrofuran; dimethylformamide / 2 h / 20 °C

6: 38 percent / DIBAL-H / toluene / 0.25 h / 0 °C

7: 64 percent / NaH / dimethylformamide / 20 °C

8: 90 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

9: 99 percent / H₂ / Raney-Ni / methanol; tetrahydrofuran / 8.5 h

10: 95 percent / K₂CO₃ / CH₂Cl₂ / 1 h / 0 °C

11: 87 percent / KH / dimethylformamide / 1 h / 0 °C

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; hydrogen; potassium hydride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; nickel; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja0013879