(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

Base Information

Chemical Name:(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate
CAS No.:1442642-27-4
Molecular Formula:C₂₆H₃₂BrClN₂O₇S
Molecular Weight:631.972
Hs Code.:

Synonyms:(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

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Chemical Property of (E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

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Technology Process of (E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

There total 4 articles about (E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 3964-56-5
4-bromo-2-chlorophenol

: 1442642-69-4
(E)-2-(hydroxymethyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

: 1442642-27-4
(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1002/adsc.201200242

Reference yield:

: C₂₁H₃₂N₂O₆S

: 1442642-27-4
(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / methanol / 24 h

2: 2,4,6-trimethyl-pyridine; (2S,5S)-2,5-bis[[(2S)-3-(2-naphthylmethyl)-1-(octyloxy)-1-oxopropan-2-ylamino]carbonyl]-1-(pyridin-4-yl)pyrrolidine / chloroform / 24 h / -60 °C

3: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 1 h / 20 °C

With 2,4,6-trimethyl-pyridine; (2S,5S)-2,5-bis[[(2S)-3-(2-naphthylmethyl)-1-(octyloxy)-1-oxopropan-2-ylamino]carbonyl]-1-(pyridin-4-yl)pyrrolidine; di-isopropyl azodicarboxylate; toluene-4-sulfonic acid; triphenylphosphine; In tetrahydrofuran; methanol; chloroform; 3: |Mitsunobu Displacement;
DOI:10.1002/adsc.201200242

Reference yield:

: 1442642-82-1
N-(2-(1,3-dihydroxypropan-2-ylidene)nonyl)-2-nitrobenzenesulfonamide

: 1442642-27-4
(E)-2-((4-bromo-2-chlorophenoxy)methyl)-3-((2-nitrophenylsulfonamido)methyl)dec-2-enyl acetate

Guidance literature:: Multi-step reaction with 2 steps

1: 2,4,6-trimethyl-pyridine; (2S,5S)-2,5-bis[[(2S)-3-(2-naphthylmethyl)-1-(octyloxy)-1-oxopropan-2-ylamino]carbonyl]-1-(pyridin-4-yl)pyrrolidine / chloroform / 24 h / -60 °C

2: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 1 h / 20 °C

With 2,4,6-trimethyl-pyridine; (2S,5S)-2,5-bis[[(2S)-3-(2-naphthylmethyl)-1-(octyloxy)-1-oxopropan-2-ylamino]carbonyl]-1-(pyridin-4-yl)pyrrolidine; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; chloroform; 2: |Mitsunobu Displacement;
DOI:10.1002/adsc.201200242