POTASSIUM HEXYLXANTHATE

Base Information

• Chemical Name: POTASSIUM HEXYLXANTHATE
• CAS No.: 2720-76-5
• Molecular Formula: C7H14 O S2 . K
• Molecular Weight: 216.41
• Mol file: 2720-76-5.mol

Synonyms:Carbonicacid, dithio-, O-hexyl ester, potassium salt (8CI); Carbonodithioic acid,O-hexyl ester, potassium salt (9CI); Xanthic acid, hexyl-, potassium salt(7CI); Hexylpotassium xanthogenate; Potassium O-hexylxanthate; Potassium hexylxanthate

Chemical Property of POTASSIUM HEXYLXANTHATE

Chemical Property:

• Vapor Pressure: 0.261mmHg at 25°C
• Boiling Point: 211.7°C at 760 mmHg
• Flash Point: 81.9°C
• PSA: 41.32000
• LogP: 2.41510

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM HEXYLXANTHATE

There total 3 articles about POTASSIUM HEXYLXANTHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.8%

→ potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; at 5 - 20 ℃; for 3.33333h;

Reference yield: 77.28%

carbon disulfide (75-15-0,12122-00-8) + hexan-1-ol (111-27-3) → potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

hexan-1-ol; With potassium hydroxide; for 4h; Schlenk technique; Inert atmosphere;

carbon disulfide; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c01110

Reference yield:

hexan-1-ol (111-27-3) → potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

With potassium hydroxide; at 25 ℃;

upstream raw materials:

hexan-1-ol

carbon disulfide

Downstream raw materials:

O-Hexyl-S-(4-brom-phenacyl)-dithiocarbonat

carbon disulfide

hexan-1-ol

Refernces

Reactions of naphthyl tellurium trihalides with some dithiocarbamates and xanthates: X-ray structure of t-shaped naphthyl tellurium 1-pyrrolidinecarbodithioate

10.1080/10426500802202063

The research investigates the reactions of naphthyl tellurium trihalides (ArTeX?, where X = Br, Cl and Ar = naphthyl) with various dithiocarbamate and xanthate ligands. The study explores the coordination chemistry of Te(II) and Te(IV) with these ligands, focusing on the formation of new naphthyl tellurium complexes. The chemicals involved include naphthyl tellurium trichloride and tribromide as starting materials, along with dithiocarbamate salts such as ammonium 1-pyrrolidinecarbodithioate and sodium dibenzyldithiocarbamate, and xanthate salts like potassium hexylxanthate. The reactions were carried out in solvents like tetrahydrofuran and methanol, resulting in the formation of naphthyl tellurium complexes with dithiocarbamate or xanthate ligands. The products were characterized using multinuclear NMR spectroscopy and elemental analysis, and the crystal structure of one of the complexes, naphthyl tellurium 1-pyrrolidinecarbodithioate, was determined by X-ray crystallography, revealing a three-coordinate T-shaped tellurium(II) geometry.