Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br

Base Information

• Chemical Name: Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br
• CAS No.: 796972-53-7
• Molecular Formula: C₄₇H₅₆BrN₂NiP
• Molecular Weight: 818.543
• Mol file: 796972-53-7.mol

Synonyms:Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br

Chemical Property of Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br

There total 1 articles about Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh₃Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.8%

dibromobis(triphenylphosphine)nickel(II) (36673-36-6,111408-20-9,14126-37-5,54053-52-0) + 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene (289618-59-3) → Ni[(N(2,6-diisopropylphenyl)C(Me)]2CH)PPh3Br (796972-53-7)

Guidance literature:

With n-butyllithium; In hexane; toluene; byproducts: LiBr, PPh3; (N2), ligand in toluene at -78°C treated under stirring with n-BuLi in hexane, warmed to room temp. overnight, treated with Ni complex, stirred for 12 h at 80°C; hot filtered, condenced (vac.), pptd., washed twice (hexane), dried (vac.), elem. anal.;

DOI:10.1016/j.molcata.2005.12.027

upstream raw materials:

dibromobis(triphenylphosphine)nickel(II)

2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene