Technology Process of C35H48O10
There total 11 articles about C35H48O10 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tetrabutyl ammonium fluoride;
In
tetrahydrofuran;
at 0 - 20 ℃;
DOI:10.1002/anie.201104681
- Guidance literature:
-
Multi-step reaction with 8 steps
1: pyridine; dmap / dichloromethane / 1 h / 0 - 20 °C
2: tetrabutyl ammonium fluoride / tetrahydrofuran / 10 h / 20 °C
3: pyridine; tributylphosphine / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere
4: dihydrogen peroxide / dichloromethane; water / 29 h / 20 °C / pH 7 / aq. phosphate buffer
5: cerium(III) chloride heptahydrate; oxalic acid / acetonitrile / 2 h / 20 °C
6: dichloromethane / 1.5 h / 20 °C
7: N-ethyl-N,N-diisopropylamine / dichloromethane / 0 - 20 °C
8: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C
With
pyridine; dmap; tributylphosphine; cerium(III) chloride heptahydrate; tetrabutyl ammonium fluoride; dihydrogen peroxide; oxalic acid; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.201104681
- Guidance literature:
-
Multi-step reaction with 10 steps
1.1: o-xylene / 20 h / 165 °C / Inert atmosphere
2.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 24 h / 20 °C
2.2: NaBO3*4H2O / 3 h / 20 °C
3.1: pyridine; dmap / dichloromethane / 1 h / 0 - 20 °C
4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 10 h / 20 °C
5.1: pyridine; tributylphosphine / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere
6.1: dihydrogen peroxide / dichloromethane; water / 29 h / 20 °C / pH 7 / aq. phosphate buffer
7.1: cerium(III) chloride heptahydrate; oxalic acid / acetonitrile / 2 h / 20 °C
8.1: dichloromethane / 1.5 h / 20 °C
9.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0 - 20 °C
10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C
With
pyridine; dmap; tributylphosphine; cerium(III) chloride heptahydrate; tetrabutyl ammonium fluoride; dihydrogen peroxide; oxalic acid; N-ethyl-N,N-diisopropylamine; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane; o-xylene; water; acetonitrile;
2.1: Hydroboration reaction;
DOI:10.1002/anie.201104681