tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane
CAS No.:114861-17-5
Molecular Formula:C₂₄H₃₁IO₄Si
Molecular Weight:538.498
Hs Code.:

Synonyms:tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

There total 3 articles about tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20031-21-4
1,2-O-isopropylidene-α-D-xylose

: 114861-17-5
tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / imidazole / dimethylformamide / 1 h / Ambient temperature

2: 1.) pyridine, (CF₃SO₂)2O; 2.) n-Bu₄NI / 1.) CH₂Cl₂, -10 deg C, 15 min; 2.) benzene, reflux, 12 h

With pyridine; 1H-imidazole; trifluoromethylsulfonic anhydride; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide;
DOI:10.1021/ja00222a028

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 114861-17-5
tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / imidazole / dimethylformamide / 1 h / Ambient temperature

2: 1.) pyridine, (CF₃SO₂)2O; 2.) n-Bu₄NI / 1.) CH₂Cl₂, -10 deg C, 15 min; 2.) benzene, reflux, 12 h

With pyridine; 1H-imidazole; trifluoromethylsulfonic anhydride; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide;
DOI:10.1021/ja00222a028

Reference yield:

: 114861-14-2
1,2-O-isopropylidene-5-O-(t-butyldiphenylsilyl)-α-D-xylofuranose

: 114861-17-5
tert-Butyl-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-diphenyl-silane

Guidance literature:: With pyridine; trifluoromethylsulfonic anhydride; tetra-(n-butyl)ammonium iodide; Yield given. Multistep reaction; 1.) CH₂Cl₂, -10 deg C, 15 min; 2.) benzene, reflux, 12 h;
DOI:10.1021/ja00222a028