Welcome to LookChem.com Sign In|Join Free
  • or

Encyclopedia

Technology Process of {closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

{closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

Base Information
  • Chemical Name:{closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9
  • CAS No.:93348-98-2
  • Molecular Formula:C9H17B9
  • Molecular Weight:222.533
  • Hs Code.:
{closo-1-(CH<sub>3</sub>)-8-(C<sub>6</sub>H<sub>5</sub>)-1,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>

Synonyms:{closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

Suppliers and Price of {closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9
Supply Marketing:
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
Total 0 raw suppliers
Chemical Property of {closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9
Chemical Property:
Purity/Quality:
Safty Information:
  • Pictogram(s):  
  • Hazard Codes: 
MSDS Files:
Useful:
Technology Process of {closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

There total 1 articles about {closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Cs{7-(CH<sub>3</sub>)-8(C<sub>6</sub>H<sub>5</sub>)-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>}
89486-20-4

Cs{7-(CH3)-8(C6H5)-7,8-C2B9H10}

{closo-1-(CH<sub>3</sub>)-8-(C<sub>6</sub>H<sub>5</sub>)-1,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>
93348-98-2

{closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

Guidance literature:
With polyphosphoric acid; In toluene; under an dry nitrogen or argon; suspn. was refluxed for 3 h and cooled to ambient temp., and the yellow organic layer was cannulated from the reaction flask; repeated washings of the polyphosphoric acid using hot toluene were essential; the toluene from the collected organic fractions were distilled under N2 until a head temp. of 114°C was attained; the remaining oil was purified by vac. sublimation (75°C); elem. anal.;
DOI:10.1021/om00120a004

Reference yield: 86.0%

{closo-1-(CH<sub>3</sub>)-8-(C<sub>6</sub>H<sub>5</sub>)-1,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>
93348-98-2

{closo-1-(CH3)-8-(C6H5)-1,8-C2B9H9

{(CH<sub>3</sub>)3NH}{nido-7-(CH<sub>3</sub>)-9-(C<sub>6</sub>H<sub>5</sub>)-7,9-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>}
93349-03-2

{(CH3)3NH}{nido-7-(CH3)-9-(C6H5)-7,9-C2B9H10}

Guidance literature:
With triethylamine; NaBH4; {(CH3)3NH}Cl; In monoethylene glycol diethyl ether; water; byproducts: B2H6; a soln. of closo-carborane in diethoxyethane was added dropwise to the rapidly stirred borohydride suspn.; the B2H6 was vented from the top of the reflux condenser under a flow of N2 into a gas scrubber contg. triethylamine in heptane, reflux for 2 h; concn. of the filtered soln. in vac. and addn. of a satd. aq. soln. of ((CH3)3NH)Cl; extn. with CH2Cl2, recrystn. from CH2Cl2/heptane and acetonitrile/heptane; elem. anal.;
DOI:10.1021/om00120a004
upstream raw materials:

Cs{7-(CH3)-8(C6H5)-7,8-C2B9H10}

Downstream raw materials:

{(CH3)3NH}{nido-7-(CH3)-9-(C6H5)-7,9-C2B9H10}

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1 Customer Service

What can I do for you?
Get Best Price

Get Best Price for 93348-98-2

Total 8 Pictures about this product