4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate

Base Information

• Chemical Name: 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate
• CAS No.: 1201796-28-2
• Molecular Formula: C₂₈H₂₁F₁₇N₂O₆S
• Molecular Weight: 836.523
• Mol file: 1201796-28-2.mol

Synonyms:4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate

Chemical Property of 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate

There total 3 articles about 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C39H42F17N3O8S (1221573-21-2) → 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate (1201796-28-2)

Guidance literature:

With trifluoroacetic acid; In methanol; at 150 ℃; for 0.333333h; Microwave irradiation;

DOI:10.1021/cc900157w

Reference yield:

2-(tert-butyloxycarbonylamino)benzoic acid (68790-38-5) → 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate (1201796-28-2)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol / 20 °C

2: trifluoroacetic acid / 0.33 h / 50 °C / Microwave irradiation

With trifluoroacetic acid; In methanol; 1: |Ugi Condensation;

DOI:10.1021/jm501120z

Reference yield:

1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-octane-1-sulfonic acid 4-formyl-2-methoxy-phenyl ester (689247-71-0) → 4-(4-butyl-2,5-dioxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]-diazepin-3-yl)-2-methoxyphenyl perfluorooctylsulfonate (1201796-28-2)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol / 20 °C

2: trifluoroacetic acid / 0.33 h / 50 °C / Microwave irradiation

With trifluoroacetic acid; In methanol; 1: |Ugi Condensation;

DOI:10.1021/jm501120z

upstream raw materials:

C₃₉H₄₂F₁₇N₃O₈S

1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-octane-1-sulfonic acid 4-formyl-2-methoxy-phenyl ester

2-(tert-butyloxycarbonylamino)benzoic acid

Downstream raw materials:

4-butyl-3-(2-methoxy-4'-vinylbiphenyl-4-yl)-3,4-dihydro-1H-benzo[e][1,4]diazepine-2,5-dione