Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

Base Information

Chemical Name:Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl
CAS No.:107474-18-0
Molecular Formula:C₂₉H₄₄ClN₂Re
Molecular Weight:642.342
Hs Code.:

Re(2,6-i-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>N)2(CH-t-Bu)Cl

Synonyms:Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

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Chemical Property of Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

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Technology Process of Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

There total 2 articles about Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 107474-17-9
Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂

: 6674-22-2,83329-50-4
1,8-diazabicyclo[5.4.0]undec-7-ene

: 107474-18-0
Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

: 78204-84-9
1,8-diazabicyclo<5.4.0>undec-7-ene hidrochloride

Guidance literature:: In diethyl ether; at -20°C, warmed to 25°C over a period of 15 min, 2 h; filtered through Celite, removal of solvent in vac., extn. (pentane), filtered through Celite, removal of solvent in vac., recrystn. (pentane); elem. anal.;
DOI:10.1016/S0277-5387(00)80695-6

Reference yield: 70.0%

: 107474-17-9
Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂

: 107474-18-0
Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In diethyl ether; byproducts: 1,8-diazabicyclo(5.4.0)undec-7-ene hydrochloride; 1.05 equiv of DBU, -30°C; crystd. from pentane; quantitative yield by (1)H NMR;
DOI:10.1021/om00147a038

Reference yield: 96.0%

: 107474-18-0
Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl

: (NH₃(C₆H₃(CH(CH₃)2)2))⁽¹⁺⁾*(ReCl₄CC(CH₃)3(NH(C₆H₃(CH(CH₃)2)2)))^(1-)=(NH₃(C₆H₃(CH(CH₃)2)2))(ReCl₄(CH₃)3CC(NH(C₆H₃(CH(CH₃)2)2)))

Guidance literature:: With HCl; In diethyl ether; HCl gas added to soln., -78°C, pptn. after 5 minutes, 25°C, 1 h; Ppt. washed with ether.;
DOI:10.1021/ja00216a071