Ru(CO)Cl(HCCHPh)(PPh₃)2

Base Information

• Chemical Name: Ru(CO)Cl(HCCHPh)(PPh₃)2
• CAS No.: 109800-33-1
• Molecular Formula: C₄₅H₃₇ClOP₂Ru
• Molecular Weight: 792.259
• Mol file: 109800-33-1.mol

Synonyms:Ru(CO)Cl(HCCHPh)(PPh₃)2

Chemical Property of Ru(CO)Cl(HCCHPh)(PPh₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CO)Cl(HCCHPh)(PPh₃)2

There total 3 articles about Ru(CO)Cl(HCCHPh)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

RuH(CO)Cl(PPh3)3*(dichloromethane) + phenylacetylene (536-74-3) → Ru(CO)Cl(HCCHPh)(PPh3)2 (109800-33-1)

Guidance literature:

In not given; byproducts: PPh3; under N2; by a react. of Ru-contg. compd. with phenylacetylene in CH2Cl2or CH2Cl2/CH3OH soln.; according to Torres M. R. et al. J. Organomet. C hem. 1986, 309, 169-177;

DOI:10.1021/ic061389f

Reference yield:

[Ru(Cl)(CO)(Et3Ge)(PPh3)2] + phenylacetylene (536-74-3) → Ru(CO)Cl(HCCHPh)(PPh3)2 (109800-33-1)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: (C2H5)3GeCCC6H5; (Ar); acetylene (1.2 equiv.) was added to soln. of Ru complex (1 equiv.)in toluene-d8 in NMR ampule cooled in liq. N2; NMR monitoring;

DOI:10.1021/om700528r

Reference yield:

[RuHCl(CO)(PPh3)3] (157072-60-1,166941-05-5,16971-33-8,61521-25-3) + phenylacetylene (536-74-3) → Ru(CO)Cl(HCCHPh)(PPh3)2 (109800-33-1)

Guidance literature:

In dichloromethane; for 1.5h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c8dt04813d

upstream raw materials:

phenylacetylene

[RuHCl(CO)(PPh₃)₃]

Downstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

[RuCl(Ph)Cl(CO)(PCy₃)₂]

[RuCl(CO)(PPh₃){SiPh(NCH₂PPh₂)₂C₆H₄}]

[RuCl(CO)(PPh₃){SiPh(NCH₂PPh₂)₂C₆H₄}]