(pentafluoro phenyl) dibromo borane

Base Information

• Chemical Name: (pentafluoro phenyl) dibromo borane
• CAS No.: 1012-83-5
• Molecular Formula: C₆BBr₂F₅
• Molecular Weight: 337.677
• Mol file: 1012-83-5.mol

Synonyms:(pentafluoro phenyl) dibromo borane

Chemical Property of (pentafluoro phenyl) dibromo borane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (pentafluoro phenyl) dibromo borane

There total 20 articles about (pentafluoro phenyl) dibromo borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(pentafluoro phenyl) ethyl mercury → (pentafluoro phenyl) dibromo borane (1012-83-5)

Guidance literature:

With boron tribromide; In dichloromethane; at -50 - 20 ℃; for 0.5h;

DOI:10.1016/S0022-328X(99)00690-7

Reference yield: 82.0%

boron tribromide (10294-33-4) + (pentafluoro phenyl) ethyl mercury → (pentafluoro phenyl) dibromo borane (1012-83-5) + bis(pentafluorophenyl)mercury(II) (973-17-1)

Guidance literature:

In dichloromethane; (Ar), at -50°C for 0.5 h, warmed to room temp. under stirring; centrifuged; not isolated, detected by NMR;

DOI:10.1016/S0022-328X(99)00690-7

Reference yield: 80.0%

boron tribromide (10294-33-4) + pentafluorophenylmercury bromide (828-72-8) → (pentafluoro phenyl) dibromo borane (1012-83-5)

Guidance literature:

equimolar amts.;

DOI:10.1021/om970433j

upstream raw materials:

di-n-butyldiphenyltin

boron tribromide

di-(pentafluoro phenyl) dibutyl stannane

pentafluorophenylmercury bromide

Downstream raw materials:

difluoro (pentafluorophenyl)borane

Pentafluorobenzene

B(C₆Cl₅)2(C₆F₅)

Refernces

• 1、 Bardin,Prikhod’ko,Shmakov,Shabalin, A. Yu.,Adonin, N. Yu.. "Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates". . p. 50 - 61. Retrieved 2020.
• 2、 Frohn,Franke,Fritzen,Bardin. "(Fluoroorgano)fluoroboranes and -fluoroborates I: Synthesis and spectroscopic characterization of potassium fluoroaryltrifluoroborates and fluoroaryldifluoroboranes". . p. 127 - 135. Retrieved 2007/10/03.