(Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester

Base Information

• Chemical Name: (Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester
• CAS No.: 183586-17-6
• Molecular Formula: C₁₃H₁₅NO₅
• Molecular Weight: 265.266
• Mol file: 183586-17-6.mol

Synonyms:(Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester

Chemical Property of (Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester

There total 1 articles about (Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methoxyfuran (25414-22-6) + acetophenone oxime (613-91-2) → (Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester (183586-17-6)

Guidance literature:

With oxygen; 5,15,10,20-tetraphenylporphyrin; In chloroform-d1; trichlorofluoromethane; at -60 ℃; for 1.5h; Irradiation;

DOI:10.1021/jo961375z

Reference yield:

(Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester (183586-17-6) → acetophenone oxime (613-91-2) + methyl (Z)-4-oxobut-2-enoate (57314-32-6)

Guidance literature:

With triphenylphosphine; In chloroform-d1; trichlorofluoromethane; at -60 ℃; for 4h; Product distribution;

DOI:10.1021/jo961375z

Reference yield:

(Z)-4-Hydroperoxy-4-[1-phenyl-eth-(E)-ylideneaminooxy]-but-2-enoic acid methyl ester (183586-17-6) → (Z)-3-(6-Methyl-6-phenyl-[1,2,4,5]trioxazinan-3-yl)-acrylic acid methyl ester

Guidance literature:

In chloroform-d1; hydrogen fluoride; at -40 - -20 ℃;

DOI:10.1021/jo961375z

upstream raw materials:

2-methoxyfuran

acetophenone oxime

Downstream raw materials:

acetophenone oxime

methyl (Z)-4-oxobut-2-enoate