(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

Base Information

Chemical Name:(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene
CAS No.:1312696-37-9
Molecular Formula:C₂₂H₃₆O₄Si
Molecular Weight:392.611
Hs Code.:

Synonyms:(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

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Chemical Property of (3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

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Technology Process of (3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

There total 3 articles about (3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1312696-36-8
(3S,4R)-3-methoxy-7-((4-methoxybenzyloxy)methyl)-4-triethylsilyloxyocta-1,7-diene

: 1312696-37-9
(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 45 ℃; for 2.5h; Inert atmosphere;
DOI:10.1016/j.tetasy.2011.03.015

Reference yield:

: C₁₈H₂₆O₄

: 1312696-37-9
(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 0 °C / Inert atmosphere

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2.5 h / 45 °C / Inert atmosphere

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2011.03.015

Reference yield:

: C₁₂H₁₅ClMgO₂

: 1312696-37-9
(3S,4R)-3-methoxy-1-((4-methoxybenzyloxy)methyl)-4-(triethylsilyloxy)cyclohex-1-ene

Guidance literature:: Multi-step reaction with 3 steps

1.1: ethylene dibromide / tetrahydrofuran / 2.5 h / Inert atmosphere

1.2: 0.17 h / Inert atmosphere

1.3: 1.5 h / Inert atmosphere

2.1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 0 °C / Inert atmosphere

3.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2.5 h / 45 °C / Inert atmosphere

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; ethylene dibromide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2011.03.015